专题:Catalytic Alkyne Reactions

This cluster of papers focuses on the use of gold as a catalyst in organic synthesis, particularly in the context of homogeneous catalysis and transition metal-catalyzed reactions. The topics covered include gold-catalyzed reactions, cycloisomerization of alkynes, synthesis of heterocycles, enantioselective synthesis, carbene complexes, hydroamination, and C-C bond formation.
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Copper-catalyzed synthesis of heterocycles via single and two-electron pathways

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Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

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Remote copper-catalyzed asymmetric [4 + 1] annulation of yne-thienyl esters with 1,3-dicarbonyls

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Unified Gold(I/III)-Catalyzed Arylative, Vinylative, and Alkynylative Lactonization via Iminium-Directed Cyclization Enabled by Hemilabile Ligands

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PBPS/Au Relay Catalysis Enables Enantioselective Synthesis of Chiral Azepines through a Cascade 1-Aza-Cope Rearrangement

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Regioselective Construction of Hexa‐Substituted Alkynyl Benzenes via Ni(0)‐Catalyzed [2+2+2] Cyclotrimerization: Mechanistic and Spectroscopic Insights

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Pd/WingPhos-Catalyzed Synthesis of γ-Amino Alcohol Derivatives with β-Axial Stereogenicity via Desymmetrization of Allenylic Cyclic Carbonates

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Highly diastereoselective synthesis of borylcyclopropanes by copper-catalyzed borylcyclopropanation of alkenes with enynones

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Nickel(0)‐Catalyzed [2+2+2] Cycloadditions of Linked Bisdiynes with Diaryl Alkynes Generates D‐π‐A‐π‐D Bis(arylethynyl)indane‐Based Organic Frameworks as Noncytotoxic Probes for Ds‐DNA/Ds‐RNA

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Enantioselective Palladium-Catalyzed Desymmetric Allenylic Substitution of Allenylic Cyclic Carbonates: Access to Axially Chiral Trisubstituted α-Allenols

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