专题：Cyclopropane Reaction Mechanisms

This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions.
最新文献
Enzyme-Catalyzed Intramolecular C–C Coupling Transformation of Nitriles

article Full Text OpenAlex

CUTTING-EDGE STRATEGIES IN THE ASYMMETRIC SYNTHESIS OF α-AMINOCYCLOPROPANE CARBOXYLIC ACIDS: ESSENTIAL SCAFFOLDS FOR DRUG DISCOVERY

article Full Text OpenAlex

Biosynthesis of Methylated Ditryptophan 2,5-Diketopeprazine Involves Cryptic N -nitrosation

article Full Text OpenAlex

Recent progress in transition-metal-catalysed intermolecular saturated C(sp 3 )–N(sp 3 ) bond formation reactions

article Full Text OpenAlex

Biocompatible organometallics for in-cell protein arylation

article Full Text OpenAlex

Formal Diels–Alder reaction of saturated carboxylic acids via C–H activation

article Full Text OpenAlex

Ring Enlargements of in Situ-Formed Cyclopropanones by Sulfoxonium Ylides: One-Pot Synthesis of Alkylidene Cyclobutanones

article Full Text OpenAlex

Intermolecular (5+3) Cycloaddition of Bicyclo[1.1.0]butanes with Oxidopyrylium

article Full Text OpenAlex

Diazo compounds: beyond carbenes as radical precursors in light-driven organic transformations

article Full Text OpenAlex

A Convergent, One-Step Biocatalytic Cascade for the Synthesis of Structurally Diverse Noncanonical Amino Acids

article Full Text OpenAlex

近5年高被引文献
Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

review Full Text OpenAlex 328 FWCI33.2397

A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres

article Full Text OpenAlex 300 FWCI43.1087

Bicyclobutanes: from curiosities to versatile reagents and covalent warheads

review Full Text OpenAlex 288 FWCI28.1946

Strain-Release Photocatalysis

review Full Text OpenAlex 248 FWCI35.9431

Cyclobutanes in Small‐Molecule Drug Candidates

review Full Text OpenAlex 237 FWCI23.5859

Beyond Bioisosteres: Divergent Synthesis of Azabicyclohexanes and Cyclobutenyl Amines from Bicyclobutanes**

article Full Text OpenAlex 235 FWCI24.1355

Late-stage Functionalization for Improving Drug-like Molecular Properties

review Full Text OpenAlex 234 FWCI33.7765

Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

article Full Text OpenAlex 229 FWCI24.1276

Rhodium-Catalyzed Asymmetric C–H Functionalization Reactions

review Full Text OpenAlex 219 FWCI31.5017

Organo/Transition-Metal Combined Catalysis Rejuvenates Both in Asymmetric Synthesis

article Full Text OpenAlex 213 FWCI15.2727