专题：Cyclopropane Reaction Mechanisms

This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions.
最新文献
Visible Light-Induced Reactions of Diazo Compounds and Their Precursors

review Full Text OpenAlex

Photocatalytic Regioselective Redox-Neutral 1,3-Oxypyridylation of Aryl Cyclopropanes

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Can Twisted Double Bonds Facilitate Stepwise [2 + 2] Cycloadditions?

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Synthesis of Fused [1,2,3]-Triazoloheteroarenes via Intramolecular Azo Annulation of N-Tosylhydrazones Catalyzed by 1,8-Diaza-bicyclo[5.4.0]undec-7-ene

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Stereodivergent Synthesis of 1,4-Dicarbonyl Compounds through Sulfonium Rearrangement: Mechanistic Investigation, Stereocontrolled Access to γ-Lactones and γ-Lactams, and Total Synthesis of Paraconic Acids

article Full Text OpenAlex

Iron-Catalyzed Oxidative Rearrangement of Cyclopropanone Hemiaminals: General Access to Pyrroloindolones from Indoles

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Phosphine-catalyzed dearomative [3+2] cycloaddition of 4-nitroisoxazoles with allenoates or Morita–Baylis–Hillman carbonates

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Synthesis of gem-Difluorinated Oxa/Azaspiro[2.4]heptanes via Palladium-Catalyzed Spirocyclopropanation

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Chiral Magnesium Complex-Catalyzed Asymmetric Cyclization of Vinyl Diazo Compounds with Phenol Derivatives via Noncarbene Pathways

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Harnessing Gold(I)-Catalyzed Hydroamination/1,3-Sulfonyl Migration Cascade for Divergent Synthesis of Isoxazolidine and Isoxazoline from O-Alkynyl Hydroxylamine

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近5年高被引文献
Toolbox for Distal C–H Bond Functionalizations in Organic Molecules

review Full Text OpenAlex 472 FWCI48.29773172

Put a ring on it: application of small aliphatic rings in medicinal chemistry

review Full Text OpenAlex 379 FWCI37.15210132

Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer

review Full Text OpenAlex 300 FWCI29.98705321

Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

review Full Text OpenAlex 295 FWCI50.72461976

Sequential C–F bond functionalizations of trifluoroacetamides and acetates via spin-center shifts

article Full Text OpenAlex 279 FWCI24.66540503

A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres

article Full Text OpenAlex 268 FWCI50.91796606

Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes

article Full Text OpenAlex 265 FWCI18.08418111

Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines

article Full Text OpenAlex 257 FWCI23.08737725

Bicyclobutanes: from curiosities to versatile reagents and covalent warheads

review Full Text OpenAlex 249 FWCI42.81501804

Mechanistic Aspects of the Palladium‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Reaction

review Full Text OpenAlex 234 FWCI20.69902788