专题：Cyclopropane Reaction Mechanisms

This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions.
最新文献
“On‐Water” Bisphosphorylation of β‐Trifluoromethyl Enones via Successive C(sp3)─F Bonds Functionalization: Synthesis of Multi‐Substituted Furans

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Construction of multifunctionalized (oxo)indoles via O-Selective interception of the zwitterionic intermediate with N=O

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Single electron transfer (SET) and iodine-atom transfer radical addition (I-ATRA) induced cyclopropanation reaction: elucidating the role of iodine

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Harnessing carbene polarity: Unified catalytic access to donor, neutral, and acceptor carbenes

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Blue Light-Induced Formal Insertion Reaction of α-Siloxy Carbene into C—H Bond of 1,3-Diketones

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Transition-Metal Free Synthesis of Cyclopropanone Ketals via Double Defluorinative Alkoxylation of gem-Difluorinated Cyclopropanes

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Impact of Induced Fitting and Secondary Noncovalent Interactions on Site-Selective and Enantioselective C–H Functionalization of Arylcyclohexanes

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Copper catalyzed cyclization of N-propargyl-N-tosyl hydrazines: Facile preparation of 1,5-disubstituted pyrazoles

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Copper(I)-Catalyzed Synthesis of 1-Amino-1,3-diene Derivatives through a Formal 1,3-Amino Migration Process

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Expedient Access to Cyclobutanones and Spirohexanones via Formal [3+1] Cycloaddition of Cyclopropanones with Sulfur Ylides

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近5年高被引文献
Toolbox for Distal C–H Bond Functionalizations in Organic Molecules

review Full Text OpenAlex 412 FWCI7.932

Put a ring on it: application of small aliphatic rings in medicinal chemistry

review Full Text OpenAlex 328 FWCI6.224

Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer

review Full Text OpenAlex 271 FWCI5.011

Sequential C–F bond functionalizations of trifluoroacetamides and acetates via spin-center shifts

article Full Text OpenAlex 258 FWCI21.684

Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

review Full Text OpenAlex 252 FWCI7.997

Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes

article Full Text OpenAlex 230 FWCI15.062

Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines

article Full Text OpenAlex 207 FWCI15.898

A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres

article Full Text OpenAlex 198 FWCI32.484

Mechanistic Aspects of the Palladium‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Reaction

review Full Text OpenAlex 198 FWCI3.438

Lightening Diazo Compounds?

article Full Text OpenAlex 193 FWCI15.995