专题:Cyclopropane Reaction Mechanisms

This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions.
最新文献
Hetero[3.1.1]propellanes

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Recent advances in catalytic asymmetric synthesis of chiral organogermanes

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Genome-guided discovery of tropansamycins: antimicrobial pentaketide ansamycins

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Selective Synthesis of Isochromene Fused Indenone or Indane Fused Indanone Derivatives Featuring with Solvent-Dependent Intra- or Intermolecular O–H Bond Carbene Insertion

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Insertion modes and origins of product selectivity in rare-earth-catalysed C–H functionalization with conjugated dienes

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Thermocatalytic CO2 cycloaddition with epoxides by d-block metal complexes: Mechanistic insights, ligand design, and catalytic trends

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Unlocking the catalytic potential of transaminase: A two-decade evolution toward green and scalable biocatalysis

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Engineered aldehyde dehydrogenases for amide bond formation

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Total Syntheses of (+)-Penicibilaenes A and B via Enantioselective Desymmetrization

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A Diazo-free Equivalent of the Unsubstituted Carbyne Cation: Straightforward Synthesis of Naphthalenes and Pyridines via [ 12/13 CH] + Insertion

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近5年高被引文献
Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

review Full Text OpenAlex 314 FWCI33.0881

A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres

article Full Text OpenAlex 290 FWCI43.6629

Bicyclobutanes: from curiosities to versatile reagents and covalent warheads

review Full Text OpenAlex 275 FWCI28.0943

Strain-Release Photocatalysis

review Full Text OpenAlex 235 FWCI35.8769

Beyond Bioisosteres: Divergent Synthesis of Azabicyclohexanes and Cyclobutenyl Amines from Bicyclobutanes**

article Full Text OpenAlex 229 FWCI24.0324

Cyclobutanes in Small‐Molecule Drug Candidates

review Full Text OpenAlex 228 FWCI23.503

Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

article Full Text OpenAlex 226 FWCI24.048

Late-stage Functionalization for Improving Drug-like Molecular Properties

review Full Text OpenAlex 216 FWCI32.8283

Rhodium-Catalyzed Asymmetric C–H Functionalization Reactions

review Full Text OpenAlex 209 FWCI31.6124

Organo/Transition-Metal Combined Catalysis Rejuvenates Both in Asymmetric Synthesis

article Full Text OpenAlex 204 FWCI15.0556