专题：Cyclopropane Reaction Mechanisms

This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions.
最新文献
Photocatalytic Access to Cyclopropanes Via Triplet Carbene Transfer from Acceptor-Acceptor Diazoalkanes

article Full Text OpenAlex

Transition-metal-catalyzed asymmetric denitrogenative transannulation

article Full Text OpenAlex

Discovery of a Heme‐Dependent Enzyme Catalyzing Nitrogen–Nitrogen Bond Formation in Kinamycin Biosynthesis

article Full Text OpenAlex

Enantioselective Thia‐Wolff Rearrangement via Cooperative Catalysis of Rhodium/Chiral Brønsted Acid: A Facile Access to Enantioenriched α‐Sulfenylated Amides †

article Full Text OpenAlex

Bifunctional Iminophosphorane Superbases Enable the Highly Enantioselective Sulfa-Michael Addition to Fully Substituted Cyclopropene Carboxylic Acid Derivatives

article Full Text OpenAlex

Copper-catalysed homo-Mannich reaction of cyclopropanol for chiral piperidine synthesis

article Full Text OpenAlex

Rh(III)-Catalyzed Imidoyl C–H Bond Activation/[4 + 2] Annulation of N -Benzimidazole Imines with Iodonium Ylides

article Full Text OpenAlex

Catalytic Asymmetric Synthesis of Chiral Allenylic Fluorides Enabled by Multiple Radical Sorting

article Full Text OpenAlex

Gold-catalyzed O-transfer involving alkynes and nitriles as a straightforward diazo-free route to oxazoles

article Full Text OpenAlex

A Three-Component Path to Amino Thiadiazoles and Amino Oxadiazoles via a Nitrilium Ylide

article Full Text OpenAlex

近5年高被引文献
Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

review Full Text OpenAlex 305 FWCI52.10020267

A catalytic alkene insertion approach to bicyclo[2.1.1]hexane bioisosteres

article Full Text OpenAlex 279 FWCI53.03954798

Bicyclobutanes: from curiosities to versatile reagents and covalent warheads

review Full Text OpenAlex 256 FWCI44.01865308

Beyond Bioisosteres: Divergent Synthesis of Azabicyclohexanes and Cyclobutenyl Amines from Bicyclobutanes**

article Full Text OpenAlex 222 FWCI37.82852999

Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

article Full Text OpenAlex 220 FWCI37.82852999

Cyclobutanes in Small‐Molecule Drug Candidates

review Full Text OpenAlex 217 FWCI36.96879068

Strain-Release Photocatalysis

review Full Text OpenAlex 214 FWCI41.27441189

Organo/Transition-Metal Combined Catalysis Rejuvenates Both in Asymmetric Synthesis

article Full Text OpenAlex 201 FWCI21.1234511

Rhodium-Catalyzed Asymmetric C–H Functionalization Reactions

review Full Text OpenAlex 191 FWCI36.64550588

Late-stage Functionalization for Improving Drug-like Molecular Properties

review Full Text OpenAlex 186 FWCI35.87402155