专题:Metal-Catalyzed Oxygenation Mechanisms

This cluster of papers focuses on the activation of dioxygen at metalloenzyme active sites, encompassing mechanisms of oxygenation reactions, proton-coupled electron transfer, non-heme iron catalysts, cytochrome P450 enzymes, high-valent intermediates, methane monooxygenase, superoxide dismutases, and ribonucleotide reductases.
最新文献
Thermodynamic Principles Behind Mechanisms and Reactivities: Hydrogen Atom Abstraction and Related Radical Reactions

article Full Text OpenAlex

Turning Off the Powerhouse: Mitochondria-Targeted DPPZ-Ru(II)/Ir(III)/Re(I) Complexes Trigger Dual Mitophagy and Apoptosis To Halt Triple-Negative Breast Cancer

article Full Text OpenAlex

Conformationally gated multisite proton-coupled electron transfer in the ribonucleotide reductase β subunit

article Full Text OpenAlex

Measurement and Control of Crossed Potentials in a Flavoprotein

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Improved Catalytic Fenton-Like Degradation of Methyl Violet Dye at Neutral pH Using the Encapsulated Tris(acetylacetonato) Iron(III) Complex inside the Zeolitic Imidazolate Framework-8

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Where Enantioselection is Set: A Mechanistic Framework for Asymmetric Hydrogen‐Atom Transfer

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Metabolic Stability of Fluorinated Small Molecules: A Physical Organic Chemistry Perspective

article Full Text OpenAlex

Effect of Fluorinated Alcohols on the Reactivity and Selectivity of the Oxoiron(V) Intermediates in C(sp 3 )–H Oxidations

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Electronic Bridges-Stabilized Fe–Cu Twin-Sites Circumvent Scaling Relationship for Robust Acidic Oxygen Reduction

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Coherent Spin Dynamics and the Magnesium-25 Isotope Effect in ATP Synthesis

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近5年高被引文献
Photoactive Copper Complexes: Properties and Applications

review Full Text OpenAlex 316 FWCI13.9203

A new era of LMCT: leveraging ligand-to-metal charge transfer excited states for photochemical reactions

article Full Text OpenAlex 184 FWCI85.2467

Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

review Full Text OpenAlex 165 FWCI10.532

Designing Artificial Metalloenzymes by Tuning of the Environment beyond the Primary Coordination Sphere

review Full Text OpenAlex 154 FWCI7.0324

Functional spectrum and specificity of mitochondrial ferredoxins FDX1 and FDX2

article Full Text OpenAlex 145 FWCI6.4541

Directed evolution of nonheme iron enzymes to access abiological radical-relay C(sp 3 )−H azidation

article Full Text OpenAlex 143 FWCI6.2614

Corroles at work: a small macrocycle for great applications

review Full Text OpenAlex 142 FWCI10.3417

Using enzymes to tame nitrogen-centred radicals for enantioselective hydroamination

article Full Text OpenAlex 125 FWCI5.6835

Biological Consequences of Vanadium Effects on Formation of Reactive Oxygen Species and Lipid Peroxidation

review Full Text OpenAlex 123 FWCI12.5443

Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C–H Activation

article Full Text OpenAlex 121 FWCI8.5556