专题:Cyclization and Aryne Chemistry

This cluster of papers explores the advances in aryne chemistry and its applications in organic synthesis, including transition-metal-free reactions, natural product total synthesis, multicomponent coupling, and the use of arynes in Diels–Alder reactions. The research also delves into the synthesis of heterocycles, regioselectivities of aryne reactions, and the role of arynes in the construction of polycyclic aromatic compounds.
最新文献
Deaminative Ring Contraction for the Modular Synthesis of Pyrido[ n ]helicenes

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Stable Vicinal Bisketene Equivalents for Aryne Diels–Alder Reactions

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Resolving Indeterminate Forms in First-Order Reaction Kinetics: A Mathematical Approach

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Gold-Catalyzed Cyclization of Pyrrole-Tethered Allenynes for the Synthesis of 4-Acylindoles and Its Application to the Ergot Alkaloid Scaffold

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Experimental and theoretical investigation of N-propargyl 3-methyl-2,6-diphenylpiperidin-4-ones: SC-XRD and DFT insights

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S2 Emission and Conformational Landscapes: System Specific Excited-State Photophysics in 1,2-Dicarbonyls

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Prediction of Atropisomerism for Drug-like Molecules

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De Novo Drug Design and Generative AI: Algorithmic Approaches to Novel Molecules

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Mechanistic insights into (3 + 2) cycloaddition of glutaraldehyde-N-Aryl nitrone with cinnamaldehyde: Electron density, docking, and molecular dynamics analysis

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Bis(gallylene) Reactivity: Insights from Reactions with Azobenzene and (PMes)₃

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近5年高被引文献
Synthesis of Arynes via Formal Dehydrogenation of Arenes

article Full Text OpenAlex 62 FWCI11.95800718

Cyclic Diaryl λ3-Chloranes: Reagents and Their C–C and C–O Couplings with Phenols via Aryne Intermediates

article Full Text OpenAlex 56 FWCI9.4571325

Advances in the synthesis of nitrogen-containing heterocyclic compounds byin situbenzyne cycloaddition

review Full Text OpenAlex 55 FWCI10.6079096

Synthesis of Sulfilimines via Aryne and Cyclohexyne Intermediates

article Full Text OpenAlex 52 FWCI10.02929635

Total synthesis of lissodendoric acid A via stereospecific trapping of a strained cyclic allene

article Full Text OpenAlex 46 FWCI8.87206984

Aryne Chemistry: Generation Methods and Reactions Incorporating Multiple Arynes

review Full Text OpenAlex 43 FWCI18.73445889

Strain-promoted reactions of 1,2,3-cyclohexatriene and its derivatives

article Full Text OpenAlex 39 FWCI7.52197226

Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines

article Full Text OpenAlex 33 FWCI6.36474576

Harnessing triaryloxonium ions for aryne generation

article Full Text OpenAlex 32 FWCI6.17187467

Skeletal Transformation of Unactivated Arenes Enabled by a Low-Temperature Dearomative (3 + 2) Cycloaddition

article Full Text OpenAlex 31 FWCI5.97900359