专题：Cyclization and Aryne Chemistry

This cluster of papers explores the advances in aryne chemistry and its applications in organic synthesis, including transition-metal-free reactions, natural product total synthesis, multicomponent coupling, and the use of arynes in Diels–Alder reactions. The research also delves into the synthesis of heterocycles, regioselectivities of aryne reactions, and the role of arynes in the construction of polycyclic aromatic compounds.
最新文献
Preparation of 2‐(Triethylsilyl)cyclohex‐1‐en‐1‐yl Trifluoromethanesulfonate as a Precursor to Cyclohexyne

other Full Text OpenAlex

Discussion Addendum for: Synthesis of Substituted Indazoles via [3 + 2] Cycloaddition of Benzyne and Diazo Compounds

other Full Text OpenAlex

Preparation of 6‐(Triethylsilyl)cyclohex‐1‐en‐1‐yl Trifluoromethanesulfonate as a Precursor to 1, 2‐Cyclohexadiene

other Full Text OpenAlex

Correction: Pronounced electronic modulation of geometrically-regulated metalloenediyne cyclization

erratum Full Text OpenAlex

Toward a Systematics for the Lowest Excited States of Heteroaromatics Enabled via Cyclic π-Conjugated Carbenes and Heteroelement Analogues.

article Full Text OpenAlex

Silver-catalyzed formal [2π+2σ] cycloaddition of bicyclobutanes with naphthols as surrogates for arynes

article Full Text OpenAlex

Acid-Catalyzed, Three-Component, Spontaneous Cascades of 1,3-Butadiynyl Propargylic Alcohols as a Route to Phthalan Derivatives

article Full Text OpenAlex

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

article Full Text OpenAlex

Piezocatalyzed Cascade Cyclization of 1,7-Enynes with Α-Keto Acids Under Ball Milling

preprint Full Text OpenAlex

Formal [4+2] Cycloaddition for Straightforward Construction of Diverse Bridged Dihydroethanobenzo[7]annulenes

article Full Text OpenAlex

近5年高被引文献
o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

review Full Text OpenAlex 302 FWCI6.225

Trends in the Diels–Alder reaction in polymer chemistry

review Full Text OpenAlex 227 FWCI4.473

Hexadehydro-Diels–Alder Reaction: Benzyne Generation via Cycloisomerization of Tethered Triynes

review Full Text OpenAlex 144 FWCI2.877

Regioselective Synthesis of 1,2,3,4‐Tetrasubstituted Arenes by Vicinal Functionalization of Arynes Derived from Aryl(Mes)iodonium Salts**

article Full Text OpenAlex 94 FWCI2.987

Leveraging Fleeting Strained Intermediates to Access Complex Scaffolds

review Full Text OpenAlex 66 FWCI1.393

Reactions of Sulfoxides with Benzynes

article Full Text OpenAlex 65 FWCI0.482

Cyclic Diaryl λ3‐Bromanes as Original Aryne Precursors

article Full Text OpenAlex 51 FWCI4.24

Heterohelicenes through 1,3-Dipolar Cycloaddition of Sydnones with Arynes: Synthesis, Origins of Selectivity, and Application to pH-Triggered Chiroptical Switch with CPL Sign Reversal

article Full Text OpenAlex 48 FWCI4.239

Challenges and opportunities to develop enediyne natural products as payloads for antibody-drug conjugates

article Full Text OpenAlex 40 FWCI2.88

Aryne Three-Component Coupling Involving CS2 for the Synthesis of S-Aryl Dithiocarbamates

article Full Text OpenAlex 40 FWCI3.277