专题:Cyclization and Aryne Chemistry

This cluster of papers explores the advances in aryne chemistry and its applications in organic synthesis, including transition-metal-free reactions, natural product total synthesis, multicomponent coupling, and the use of arynes in Diels–Alder reactions. The research also delves into the synthesis of heterocycles, regioselectivities of aryne reactions, and the role of arynes in the construction of polycyclic aromatic compounds.
最新文献
Application of the intramolecular Diels-Alder vinylarene (IMDAV) reaction for the synthesis of benzo-and carbocyclofuroisoindolecarboxylic acids and its limitations

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Would the tandem sequential cycloaddition reactions of functionalized acetylene, cyclopentadienyl derivatives, and phenyl azide for the formation of norbornene 1,2,3-triazolines proceed via the [4 + 2]/[3 + 2] or [3 + 2]/[4 + 2] reaction sequences? a DFT mechanistic study

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Exclusive Papers of the Editorial Board Members of the Organic Chemistry Section of Molecules

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Ynimines as versatile precursors to 2-imido- and 2-amido-1,3-dienes for stereodivergent diels–alder reactions

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Skeletal Editing of Benzocyclobutenols toward Beonzo[b]furans

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Levetiracetam (isotopically labeled with 11C) synthesis

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Enantioselective Desymmetrization of Diynes

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Next-Generation Janus Kinase Inhibitors: Integrating Synthetic Innovation, Structural Biology, and Computational Design for Precision Drug Discovery

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Synthesis, Structure, and Thermal Properties of Bifunctional Arylbuta-1,3-Diynes

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Unbiased molecular dynamics for the direct determination of catalytic reaction times: Paving the way beyond transition state theory

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近5年高被引文献
Synthesis of Arynes via Formal Dehydrogenation of Arenes

article Full Text OpenAlex 66 FWCI10.1579

Cyclic Diaryl λ3-Chloranes: Reagents and Their C–C and C–O Couplings with Phenols via Aryne Intermediates

article Full Text OpenAlex 59 FWCI6.1217

Advances in the synthesis of nitrogen-containing heterocyclic compounds byin situbenzyne cycloaddition

review Full Text OpenAlex 59 FWCI9.0523

Synthesis of Sulfilimines via Aryne and Cyclohexyne Intermediates

article Full Text OpenAlex 57 FWCI8.7577

Total synthesis of lissodendoric acid A via stereospecific trapping of a strained cyclic allene

article Full Text OpenAlex 48 FWCI7.3646

Aryne Chemistry: Generation Methods and Reactions Incorporating Multiple Arynes

review Full Text OpenAlex 48 FWCI12.8292

Strain-promoted reactions of 1,2,3-cyclohexatriene and its derivatives

article Full Text OpenAlex 40 FWCI6.1067

Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines

article Full Text OpenAlex 39 FWCI5.9921

Harnessing triaryloxonium ions for aryne generation

article Full Text OpenAlex 34 FWCI5.1674

Skeletal Transformation of Unactivated Arenes Enabled by a Low-Temperature Dearomative (3 + 2) Cycloaddition

article Full Text OpenAlex 31 FWCI4.7768