专题：Cyclization and Aryne Chemistry

This cluster of papers explores the advances in aryne chemistry and its applications in organic synthesis, including transition-metal-free reactions, natural product total synthesis, multicomponent coupling, and the use of arynes in Diels–Alder reactions. The research also delves into the synthesis of heterocycles, regioselectivities of aryne reactions, and the role of arynes in the construction of polycyclic aromatic compounds.
最新文献
Organocatalytic Enantioselective [4 + 4] Cycloadditions of Furan Ortho‐Quinodimethanes

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Organocatalytic Enantioselective [4 + 4] Cycloadditions of Furan Ortho‐Quinodimethanes

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meta-Substituted Diaryliodonium Salts Enabled Aryne 1,2,4′-Trifunctionalization

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Pyrazole-Enabled Controlled SNAr Polymerization of Arynes

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Behavior of modified Hexa-2,4-diyne-1,6-dioles in acidic media – A balance between cyclobutenes and diarylvinylfuran-3(2H)-ones

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Intermolecular Diels–Alder Reactions

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When π–π Stacking Outcompetes Hydrogen Bonding: Pre-Reactive Intermediates in the Furan–Acrolein Diels–Alder Reaction

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Macrocycles Composed of Biphenylene and Butadiyne Units with Antiaromatic Character

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Effect of Chalcogen-Phosphorus Substituents on Enediynes Undergoing the Bergman Cyclization

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Cover Feature: Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4‐diides: Interplay Between Diradical Character and Aromaticity

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近5年高被引文献
o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

review Full Text OpenAlex 314 FWCI6.224

Trends in the Diels–Alder reaction in polymer chemistry

review Full Text OpenAlex 239 FWCI4.471

Hexadehydro-Diels–Alder Reaction: Benzyne Generation via Cycloisomerization of Tethered Triynes

review Full Text OpenAlex 146 FWCI2.876

Regioselective Synthesis of 1,2,3,4‐Tetrasubstituted Arenes by Vicinal Functionalization of Arynes Derived from Aryl(Mes)iodonium Salts**

article Full Text OpenAlex 95 FWCI2.987

Leveraging Fleeting Strained Intermediates to Access Complex Scaffolds

review Full Text OpenAlex 69 FWCI1.393

Reactions of Sulfoxides with Benzynes

article Full Text OpenAlex 65 FWCI0.482

Cyclic Diaryl λ3‐Bromanes as Original Aryne Precursors

article Full Text OpenAlex 56 FWCI4.24

Heterohelicenes through 1,3-Dipolar Cycloaddition of Sydnones with Arynes: Synthesis, Origins of Selectivity, and Application to pH-Triggered Chiroptical Switch with CPL Sign Reversal

article Full Text OpenAlex 49 FWCI4.24

Origins of Endo Selectivity in Diels–Alder Reactions of Cyclic Allene Dienophiles

article Full Text OpenAlex 43 FWCI3.276

Challenges and opportunities to develop enediyne natural products as payloads for antibody-drug conjugates

article Full Text OpenAlex 40 FWCI2.88