专题：Chemical Reactions and Mechanisms

This cluster of papers explores the phenomenon of quantum tunneling in chemical reactions, focusing on nitrenes, carbenes, photochemistry, and organic synthesis. It delves into topics such as heavy-atom tunneling, matrix isolation, and the interplay of experimental and computational chemistry in understanding tunneling control of reactions.
最新文献
Time-Resolved Study of Light-Induced Ground-State Proton Transfer from an Acidic Medium to 4-Nitrophenolate

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Isomerization of Methylhydroxycarbene in Isolation and Mediated by Its Interactions with Ammonia and Formic Acid

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Intermolecular Interactions in Crystals Modulate Intramolecular Excited State Proton Transfer Reactions

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Impact of Bulky Substituents on the Singlet Arylnitrene Ring Enlargement

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Product and Mechanistic Insights into the Ozonolysis of Δ3-Carene

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Deciphering the Photochemistry of Thionylimide (HNSO): Isomers and Tunneling-Controlled Reactions

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Mechanisms and Synthetic Applications of Cyclic, Nonstabilized Isodiazenes: Nitrogen-Atom Insertion into Pyrrolidines and Related Rearrangements

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“Quantum Tango” and Inverse Isotope Effect in Furan–Water Complex Unraveled by Microwave Spectroscopy and Instanton Theory

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Rapid access to arynes from aryl triflates using a non-competitive, commercially available amide base

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Discovery of anthraquinone-triazene derivatives as novel antitumor agents causing DNA damage

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近5年高被引文献
Best‐Practice DFT Protocols for Basic Molecular Computational Chemistry**

review Full Text OpenAlex 514 FWCI15.68

Electronic Spectra of Polyatomic Molecules

book-chapter Full Text OpenAlex 367 FWCI17.71

Chemical reactivity from an activation strain perspective

review Full Text OpenAlex 105 FWCI1.453

The Chemistry of DPPH· Free Radical and Congeners

review Full Text OpenAlex 98 FWCI1.753

Carbonic anhydrase II deficiency

article Full Text OpenAlex 93 FWCI2.801

Targeted activation in localized protein environments via deep red photoredox catalysis

article Full Text OpenAlex 85 FWCI9.708

Isolation and reactivity of an elusive diazoalkene

article Full Text OpenAlex 84 FWCI7.132

Synthesis and Characterization of Binary, Highly Endothermic, and Extremely Sensitive 2,2′-Azobis(5-azidotetrazole)

article Full Text OpenAlex 82 FWCI12.325

Mechanistic Understanding of Superoxide Radical-Mediated Degradation of Perfluorocarboxylic Acids

article Full Text OpenAlex 76 FWCI10.03

A simple yet multifaceted 90 years old, evergreen enzyme: Carbonic anhydrase, its inhibition and activation

review Full Text OpenAlex 68 FWCI3.853