专题:Chemical Reactions and Mechanisms

This cluster of papers explores the phenomenon of quantum tunneling in chemical reactions, focusing on nitrenes, carbenes, photochemistry, and organic synthesis. It delves into topics such as heavy-atom tunneling, matrix isolation, and the interplay of experimental and computational chemistry in understanding tunneling control of reactions.
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Synthesis of new derivatives of N,N-dimethylpropylenediamine containing 1,3-dioxolane and gem-dichlorocyclopropane fragments

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Positional Alkene Photo-Isomerization

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Biosynthesis of Methylated Ditryptophan 2,5-Diketopeprazine Involves Cryptic N -nitrosation

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Metastable Intermediates (Isoindenes, Isofluorenes, and Isobenzofurans) from Alkyne Precursors via Free Carbenes

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Crystalline nitrogen chain radical anions

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Diazo compounds: beyond carbenes as radical precursors in light-driven organic transformations

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Organic Chemistry in the Creation of Molecules with Practically Useful Properties

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Sterically Hindered Diazene Derivative and its Dihydrochloride Salt: A DFT-based Investigation of Structural and Electronic Properties

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Reductive Ring Expansion of Lactams with Azlactones

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Supplementary material to "Wintertime photochemistry of acyl peroxynitrates and ozone in South Korea during the ASIA-AQ campaign"

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